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HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryGOC

The number of sigma electrons in toluene are

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryGOC

Which of the following represents the given mode of hybridisation sp -sp -sp-sp from left to right ? (a) H C CH C N

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryGOC

The IUPAC name of the following compound is

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryGOC

Which of the following orders is correct for the stability of these carbocations ?

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryGOC

The molecular formula of diphenyl methane is C 13H How many structural isomers are possible when one of the hydrogen is replaced by a chlorine atom?

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryGOC

The geometrical isomerism is shown by (a) (b) (c) (d)

HARDMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryGOC

The type of isomerism observed in urea molecule is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Among the plots of P versus V, as given below, which one corresponds to Boyle’s law ? (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Calculate the number of moles in the glass bulb shown in figure at 300 K. Given : density of glycerine = 2.72 g/mL; density of mercury = 13.6g/mL

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Which of the following is a correct plot of the volume of fixed amount of ideal gas as a function of temperature (at constant pressure) ? (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion : The pressure of a gas is inversely proportional to the volume at constant temperature and n. Reason : The gas volume is directly proportional to n at constant temperature and pressure.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion :Kinetic energy and momentum of ideal gas molecules are conserved during intermolecular collision. Reason :Collision among real gas molecules is inelastic.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion: For a real gas, the gas pressure is always less than the pressure calculated from kinetic theory of gases. Reason: In kinetic theory, both molecular volumes and intermolecular attractions were ignored.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion :Gases do not liquefy above their critical temperature, whatever the high pressure is applied. Reason :Above critical temperature, molecular speed is high and intermolecular force cannot hold the molecules t…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion :Above critical temperature liquid state cannot be observed. Reason :Above critical temperature, the average kinetic energy of a molecule is always greater than the maximum kinetic energy a molecule can poss…

HARDINTEGERIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion:CH₄, CO₂ has value of Z (compressibility factor) less than one at 0ºC. Reason :Z < 1 is due to the attractive forces dominate among the molecules.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion: Compressibility factor (Z) for non- ideal gases may be less than or greater than 1. Reason: Non-ideal gases always exert higher pressure than expected.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion :According to kinetic theory of gases, gas molecules occupy some space. Reason :Gases can be liquefied and solidified.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion: A lighter gas diffuses more rapidly than a heavier gas. Reason: At a given temperature, the rate of diffusion of a gas is inversely proportional to the density.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion: According to Charles’ law, for a give amount of an ideal gas at a given pressure, plot of gas volume versus absolute temperature is a straight line passing through origin. Reason: Gaseous volume never vanis…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Assertion :For a given amount of an ideal gas, a plot of pressure (p) versus (1/V) is a straight line at a constant temperature. Reason :A given amount of an ideal gas at a constant temperature obeys Boyle’s law.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Gases possess characteristic critical temperature which depends upon the magnitude of intermolecular forces between the particles. Following are the critical temperatures of some gases Gases : H₂ He O₂ N₂ Critical tem…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

NH₃ can be liquefied at ordinary temperature without the application of pressure. But O₂ cannot, because

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

For NH₃ gas Z < 1. So the volume occupied by one mole of NH₃ (Vm) at STP is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous state

Five grams each of the following gases at 87 °C and 750 mm pressure are taken. Which of them will have the least volume ?

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