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HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The solubility of LiOH in a solution with pH = 8 is (Ksp = 1.8 × 10–12)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion (A): pH of HCl solution is less than that of acetic acid of the same concentration. Reason (R):  In  equimolar  solutions,  the  number  of titrable protons present in HCl in less than that present in acetic…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

When one drop of a concentrated HCl is added to 1 L of pure water at 25ºC, the pH drops suddenly from 7 to 4. When the second drop of the same acid is added, the pH of the solution further drops to about

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The pH of 10–5 M HCl solution if 1 ml of it is diluted to 1000 ml is :

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

A buffer is prepared by adding 0.30 mol CH₃COONa to 2.0  L  of  a  0.10  M  CH₃COOH  solution.  Calculate the eq K /c (x y) eq K c/(xy) 1/(x y) x y 1 x y eq K /c x y eq K /xyc pH  after  0.030  mol  HCl  are  added  t…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Which  pair  of  reagents,  mixed  in  the  appropriate proportion, could make a buffer in pH 3-4 range ?

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

How many milliliters of 0.250 M NH₄Cl would have to be  added  to  450  mL  of  0.350  M  KOH  in  order  to produce a buffer solution with a pH of 9.10? (Kb(NH₃) = 1.8 × 10–5)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

How  many  milliliters  (mL)  of  a  0.0500  M  NaOH  (a strong  base)  solution  should  be  added  to  1.00  L  of 0.100 M H₃PO₄, solution to produce a buffer of pH = 2.00 ? For H₃PO₄, a K = 6.67 × 10–3 Given: H PO …

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

H S aq H aq HS aq ;K 9.5 10 x HS aq H aq S aq ;K 1.0 10 x Given  the  equilibrium  constants  provided  what  is  the equilibrium constant for the reaction: S (aq) 2H (aq) H S(aq) K = ?

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The correct order of increasing [H₃O⁺] in the following aqueous solution is:

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Calculate  the  concentration  of  H⁺  ion  in  mol/L  of 0.010M solution of NH₄Cl? (Kb = 1.8 × 10–6)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Ksp of Mg (OH)₂ is 1 × 10–12. 0.01 M Mg (OH)₂ will be precipitating at the limiting pH :

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The solubility products of MA, MB, MC and MD are 1.8 × 10–10, 4 × 10–3, 4 × 10–8 and 6 × 10–5 respectively. If  a  0.01  M  solution  of  MX  is  added  dropwise  to  a mixture containing A–, B–, C– and D– ions then t…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion (A): H₂SO₄ acts as a base in the presence of HClO₄. Reason (R): Perchloric  acid  is  stronger  acid  than H₂SO₄.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: Addition  of  HCl(aq.)  to  HCOOH(aq.) decreases the ionization of HCOOH. Reason:  Common  ion  effect  of  H⁺  ion,  reduces  the ionization of HCOOH.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: pH  of  water  increases  with  an  increase  in temperature. Reason: Kw  of  water  increases  with  increase  in temperature.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: pH of 10–8 M HCl lies between 6 and 7. Reason:  For  very  dilute  solutions  of  acids,  H⁺  ion contribution from water is also taken into consideration.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: If a K  of HA is 10–3 and a K  of HB is 10 at 25ºC, pH of an aqueous solution of HB will be one unit greater than pH of equimolar solution of HA. Reason:  For  weak  acids,  both  concentration  and ionizat…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryHydrogen

Which of the following reaction produces hydrogen?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryHydrogen

Match the column I with column II and mark the appropriate choice. Column I Column II (A) Clark’s method (i) Na₆P₆O₁₈ (B) Calgon’s method (ii) NaAlSiO₄ (C) Ion-exchange method (iii) RSO₃H (D) Synthetic resins method (…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryHydrogen

Consider the following statements: 1. Atomic hydrogen is obtained by passing hydrogen through an electric arc. 2. Hydrogen gas will not reduce heated aluminium oxide. 3. Finely divided palladium absorbs large volume o…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryHydrogen

Match the column I with column II and mark the appropriate choice. Column I Column II (A) NaH (i) Interstitial hydride (B) CH₄ (ii) Molecular hydride (C) VH₀.56 (iii) Ionic hydride (D) B₂H₆ (iv) Electron-deficient hyd…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryHydrogen

The molecular formula of a commercial resin used for exchanging ions in water softening is C₈H₇SO₃Na (Mol. wt. 206). What would be the maximum uptake of Ca²⁺ ions by the resin when expressed in mole per gram resin?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryHydrogen

Match the column I with column II and mark the appropriate choice. Column I Column II (A) Syngas (i) Na₆P₆O₁₈ (B) Calgon (ii) NaAlSiO₄ (C) Permutit (iii) CO + H₂ (D) Producer gas (iv) CO + N₂

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryHydrogen

During hydrate formation from aqueous solution, water can be associated in different forms. Indicate the wrong combination. (i) Coordinated water – [Cr(H₂O)₆]3+ 3Cl– (ii) Interstitial water – BaCl₂.2H₂O (iii) Hydrogen…

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