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HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The solubility of AgCl is maximum in

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The solubility of LiOH in a solution with pH = 8 is (Ksp = 1.8 × 10–12)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Assertion (A): pH of HCl solution is less than that of acetic acid of the same concentration. Reason (R):  In  equimolar  solutions,  the  number  of titrable protons present in HCl in less than that present in acetic…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Assertion: If HA and HB are two weak non-basic acids with Ka(HA)  < Kb(HB), then, the aqueous solution  of NaA will have higher pH than pH of aqueous solution of NaB of same concentration. Reason: Conjugate base of  a…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH₃COOAg is diluted, then its degree of hydrolysis increases. Reason:  Silver  acetate  is  the  salt  of  weak  acid  and weak base; its degree of hydrolysis does not depend on th…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH₃COONH₄ is diluted, then its degree of hydrolysis increases. Reason:  Ammonium  acetate  is  the  salt  of  weak  acid and  weak  base;  its  degree  of  hydrolysis  does  not de…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Assertion: Aqueous  solution of  ammonium  carbonate is basic. Reason: Acidic or Basic nature of a salt solution of a salt  of  weak  acid  and  weak  base  depends  on  Ka  and Kb of the acid and base forming it.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Assertion: If a K  of HA is 10–3 and a K  of HB is 10 at 25ºC, pH of an aqueous solution of HB will be one unit greater than pH of equimolar solution of HA. Reason:  For  weak  acids,  both  concentration  and ionizat…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Assertion: pH of 10–8 M HCl lies between 6 and 7. Reason:  For  very  dilute  solutions  of  acids,  H⁺  ion contribution from water is also taken into consideration.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

How  many  milliliters  (mL)  of  a  0.0500  M  NaOH  (a strong  base)  solution  should  be  added  to  1.00  L  of 0.100 M H₃PO₄, solution to produce a buffer of pH = 2.00 ? For H₃PO₄, a K = 6.67 × 10–3 Given: H PO …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

How many milliliters of 0.250 M NH₄Cl would have to be  added  to  450  mL  of  0.350  M  KOH  in  order  to produce a buffer solution with a pH of 9.10? (Kb(NH₃) = 1.8 × 10–5)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Which  pair  of  reagents,  mixed  in  the  appropriate proportion, could make a buffer in pH 3-4 range ?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A buffer is prepared by adding 0.30 mol CH₃COONa to 2.0  L  of  a  0.10  M  CH₃COOH  solution.  Calculate the eq K /c (x y) eq K c/(xy) 1/(x y) x y 1 x y eq K /c x y eq K /xyc pH  after  0.030  mol  HCl  are  added  t…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The pH of 10–5 M HCl solution if 1 ml of it is diluted to 1000 ml is :

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

When one drop of a concentrated HCl is added to 1 L of pure water at 25ºC, the pH drops suddenly from 7 to 4. When the second drop of the same acid is added, the pH of the solution further drops to about

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A student dissolved 0.100 mol of an unknown monoprotic acid, HA, in sufficient water to make 1.00 L of solution. She measured the pH of the solution as pH = 2.60. Of the following, the acid HA is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

For  a  “c  molar”  concentrated  solution  of  a  weak electrolyte AxBy, the degree of dissociation is given as (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

What is the equilibrium [OH–] in 0.1413 M H₂CO₃ ? H CO H O H O HCO (Ka = 4.30 ×10–7)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

A mixture of weak acid is 0.1 M in HCOOH a K 1.8 10 x and 0.1 M in HOCN a K 3.1 10 x Hence, [H O ]  is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The equilibrium constant for this reaction is approximately 10–3. HPO (aq.) HCO (aq.) H PO (aq.) CO (aq.) Which is the strongest conjugate base in this reaction? (a) HPO (aq.) (b) HCO (aq.) (c) H PO (aq.) (d) CO (aq.)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Consider  the  following  reaction  which  proceeds predominantly forward HSO NH NH SO From the information given it is clear that (a) HSOis a stronger acid than NH.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

H S aq H aq HS aq ;K 9.5 10 x HS aq H aq S aq ;K 1.0 10 x Given  the  equilibrium  constants  provided  what  is  the equilibrium constant for the reaction: S (aq) 2H (aq) H S(aq) K = ?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

The correct order of increasing [H₃O⁺] in the following aqueous solution is:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Calculate  the  concentration  of  H⁺  ion  in  mol/L  of 0.010M solution of NH₄Cl? (Kb = 1.8 × 10–6)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibrium

Ksp of Mg (OH)₂ is 1 × 10–12. 0.01 M Mg (OH)₂ will be precipitating at the limiting pH :

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