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HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Anodising can be done by electrolysing dilute H₂SO₄ with aluminium as anode. This results in :

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : PbI₄ is a stable compound. Reason : Iodide stabilizes higher oxidation state.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : SiF - is known but SiCl - is not. Reason : Size of fluorine is small and its lone pair of electrons interacts with d-orbitals of Si strongly.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : Between SiCl₄ and CCl₄, only SiCl₄ reacts with water. Reason : SiCl₄ is ionic and CCl₄ is covalent.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : Pb⁴⁺ compounds are stronger oxidising agents than Sn²⁺ compounds. Reason : The higher oxidation states for the group 14 elements are more stable for the heavier members of the group due to ‘inert pair effe…

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : In water, orthoboric acid behaves as a weak monobasic acid. Reason : In water, orthoboric acid acts as a proton donor.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : Boron is p block element. Reason : Last electron entres in p sub shell.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : Boron always forms covalent bond. Reason : The small size of B³⁺ favours formation of co- valent bond.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : AlF₃ is soluble in KF but addition of BF₃ brings its precipitation. Reason BF₃ is more acidic than AlF₃.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : BF₃ is a weaker Lewis acid than BCl₃. Reason : BF₃ molecule is stabilized to a greater extent than BCl₃ by B—F p-bonding.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

Assertion : Al(OH)₃ is amphoteric in nature. Reason : Al—O and O—H bonds can be broken with equal ease in Al (OH)₃.

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

When an inorganic compound (X) having 3C—2e as well as 2c—2e bonds reacts with ammonia gas at a cer- tain temperature, gives a compound (Y), isostructural with benzene. Compound (X) with ammonia at a high temperature …

HARDMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp-Block (group 13 and 14)

A metal X reacts with aqueous NaOH solution to form Y and a highly inflammable gas. Solution Y is heated and CO₂ is poured through it. Z precipitates out and Na₂CO₃ is formed. Z on heating gives Al₂O₃, Identify X, Y a…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

NH₄Cl is preferred to NaCl for the preparation of HCl by the action of concentrated H₂SO₄ because

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Assertion: The electronic structure of O₃ is Reason: The following structure is not allowed because the octet around O cannot be expanded.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Assertion: O₃ has a fishy smell. Reason: It absorbs red part of the visible light.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Assertion: Although PF₅, PCl₅ and PBr₅ are known, the pentahalides of nitrogen have not been observed. Reason: Phosphorous has a lower electronegativity than nitrogen.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Assertion: HNO₃ is a stronger acid than HNO₂. Reason: In HNO₃ there are two nitrogen to oxygen bonds whereas in HNO₂ there is only one.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The shape of XeO₂F₂ molecule is:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

The oxidation state of xenon atom in XeF₄, HXeO and Na₄XeO₆ are respectively:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

When F₂ reacts with hot and conc. alkali, then following will be obtained: (i) OF₂ (ii) O₂ (iii) H₂O (iv) NaF

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Dry Cl₂ reacts with dry SO₂ to form:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

Which of the following oxides of chlorine is obtained by passing dry chlorine over silver chlorate at 900C?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

HClO₄ + P₂O₅ → (A) + (B)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp -Block Elements (group 15-18)

When iodine is treated with a mixture of NaF, NaBr and NaCl in water, it gives

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