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MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 2H O g 2H g O g → ∆H = 571.6 KJ fH of water is :

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

∆H for the reaction, SO g O g SO g ∆H = –98.3 kJ If the enthalpy of formation of SO₃(g) is –395.4 kJ then the enthalpy of formation of SO₂(g) is :

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

105. (∆U – ∆H) for the formation of NH₃ from N₂ and H₂ is :

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The molar heat capacity of water at constant pressure, C, is 75J K-1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of water is. (2003)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

If the bond energies of H–H, Br–Br, and H–Br are 433, 192 and 364 kJ mol–1 respectively, the H for the reaction 2(g) 2(g) (g) H Br 2HBr → is (2004)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The absolute enthalpy of neutralisation of the reaction: (g) (g) 2(aq) (l) MgO 2HCl MgCl H O → Will be (2005)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

A reaction occurs spontaneously if (2005)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The enthalpy and entropy change for the reaction: 2(l) 2(g) (g) Br Cl 2BrCl → are 30 kJ mol–1 and 105JK–1 mol–1 respectively. The temperature at which the reaction will be in equilibrium is (2006)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Consider the following reaction –1 (aq) (aq) (l) –1 2(g) 2(g) (l) 2(g) 2(g) (g) (l) –1 2(g) 2(g) 2(g) (l) –1 (i)H OH H O , H X kJ mol (ii)H 1/ 2O H O , H X kJ mol (iii)CO H CO H O , H X kJ mol (iv)C H 5 / 2O 2CO H O ,…

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the gas phase reaction, 5(g) 3(g) 2(g) PCl PCl Cl Which of the following conditions are correct? (2008)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Bond dissociation enthalpy of H₂ Cl₂, and HCl are 434, 242 and 431 kJ mol respectively. Enthalpy of formation of HCl is (2008)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Gaseous system is placed with pressure P₁, volume V₁ and  temperature  T1,  it  has  undergone  thermodynamic changes where temperature is remaining constant, it is

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Based on the first law of thermodynamics, which one of the following is correct?

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

U q w , is mathematical expression for

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

According to the first law of thermodynamics, U q w . In special cases the statement can be expressed in different ways. Which of the following is not a correct expression?

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Two moles of Helium gas undergo a reversible cyclic process as shown in figure. Assuming gas to be ideal. What is the work done for the process C to D?

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

E is always positive, when

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

An ideal gas is taken around the cycle ABCA as shown in P-V diagram The net work done by the gas during the cycle is equal to:

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

An ideal gas receives 10 J of heat in a reversible isothermal expansion. Then the work done by the gas:

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas is initially at 0°C and 1 atm pressure. If it absorbs 1000 cal heat during a reversible isothermal expansion, what will be its final volume?

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The maximum work obtained by an isothermal reversible expansion of 1 mole of an ideal gas at 27°C from 2.24 to 22.4 L is (R = 2 cal)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

16g of oxygen gas expands isothermally and reversibly at 300 K from 10 dm3 to 100 dm3. The work done is (in J)

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The work done during the expansion of a gas from a volume of 4dm3 to 6 dm3 against a constant external pressure of 3 atm is

MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The following two reactions are known Fe₂O₃(s) + 3CO(g) → 2Fe(s) + 3CO₂(g); ∆H = –26.8 kJ FeO(s) + CO(g) → Fe(s) + CO₂(g); ∆H = – 16.5 kJ The value of ∆H for the following reaction Fe₂O₃(s) + CO(g) → 2FeO(s) + CO₂(g) …

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