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MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. If the standard free energy difference is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamond a…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 2H O g 2H g O g → ∆H = 571.6 KJ fH of water is :

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

When 0.5 g of sulphur is burnt to SO₂ 4.6 kJ of heat is liberated. What is the enthalpy of formation of sulphurdioxide?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The heat of formation of Fe O s is –824.2 kJ mol–1. ∆H for the reaction. 2Fe O s 4Fe s 3O g → is:

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the reaction, 8 g 2 g 2 g l C H 5O 3CO 4H O → at constant temperature, H E is (2003)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The molar heat capacity of water at constant pressure, C, is 75J K-1. When 1.0 kJ of heat is supplied to 100 g of water which is free to expand, the increase in temperature of water is. (2003)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The densities of graphite and diamond at 298 K are 2.25 and 3.31 g cm–3, respectively. The standard free energy difference ( G ) is equal to 1895 J mol–1, the pressure at which graphite will be transformed into diamon…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The absolute enthalpy of neutralisation of the reaction: (g) (g) 2(aq) (l) MgO 2HCl MgCl H O → Will be (2005)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Identify the correct statement for change of Gibbs’ energy for a system system ( G ) at constant temperature and pressure. (2006)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The enthalpy and entropy change for the reaction: 2(l) 2(g) (g) Br Cl 2BrCl → are 30 kJ mol–1 and 105JK–1 mol–1 respectively. The temperature at which the reaction will be in equilibrium is (2006)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Given that bond energies of H – H and Cl – Cl are 430 kJ mol–1 and 240 kJ mol–1 respectively and f H for HCl is-90 kJ mol–1 bond enthalpy of HCl is (2007)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

For the gas phase reaction, 5(g) 3(g) 2(g) PCl PCl Cl Which of the following conditions are correct? (2008)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Gaseous system is placed with pressure P₁, volume V₁ and  temperature  T1,  it  has  undergone  thermodynamic changes where temperature is remaining constant, it is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Based on the first law of thermodynamics, which one of the following is correct?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

U q w , is mathematical expression for

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

According to the first law of thermodynamics, U q w . In special cases the statement can be expressed in different ways. Which of the following is not a correct expression?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

Two moles of Helium gas undergo a reversible cyclic process as shown in figure. Assuming gas to be ideal. What is the work done for the process C to D?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

E is always positive, when

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

An ideal gas is taken around the cycle ABCA as shown in P-V diagram The net work done by the gas during the cycle is equal to:

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

An ideal gas receives 10 J of heat in a reversible isothermal expansion. Then the work done by the gas:

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas is initially at 0°C and 1 atm pressure. If it absorbs 1000 cal heat during a reversible isothermal expansion, what will be its final volume?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The maximum work obtained by an isothermal reversible expansion of 1 mole of an ideal gas at 27°C from 2.24 to 22.4 L is (R = 2 cal)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

16g of oxygen gas expands isothermally and reversibly at 300 K from 10 dm3 to 100 dm3. The work done is (in J)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The work done during the expansion of a gas from a volume of 4dm3 to 6 dm3 against a constant external pressure of 3 atm is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and Thermochemistry

The heat liberated when 1.89 g of benzoic acid is burnt in a bomb calorimeter at 25 °C increases the temperature of 18.94 kg of water by 0.632 °C. If the specific heat of water at 25 °C is 0.998 cal/g-deg, the value o…

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