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MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

The freezing point depression constant f K of benzene is 5.12 K kg mol-1. The freezing point depression for the solution of molality 0.078 m containing a non- electrolyte solute in benzene is (rounded off upto two dec…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

25 mg of CaCO₃ is dissolved in 5 L of solution. The approximate concentration of solution is

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

The normality of 10% H₂SO₄ solution (d = 1.1g/cm3) is

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

Calculate the molarity of H₂SO₄ solution if the normality of H₂SO₄ Solution is 0.4 N.

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

At a particular temperature, the vapour pressures of two liquids A and B are respectively 120 and 180 mm of Hg respectively. If 2 moles of A and 3 moles of B are mixed to form an ideal solution, the vapour pressure of…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

If the elevation in boiling point of a solution of 10 g of solute (molecular weight = 100) in 100 g of water is b T , the ebulliscopic constant of water is (Manipal 2010)

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

b b o cal C kg mol gm K K x x x

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

A solution containing 1.8 g of a compound (empirical formula CH₂O) in 40 g of water is observed to freeze at –0.465 °C. The molecular formula of the compound is (Kf of water = 1.86 kg K mol–1)

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

An aqueous solution of NaCl shows the depression of freezing point of water equal to 0.372 K. The boiling point of BaCl₂ solution of same molality will be [Kf (H₂O)= 1.86 K kg mol–1; Kb(H₂O) = 0.52 K kg mol–1]

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

Which of the following 0.10 m aqueous solutions will have the lowest freezing point?

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

Which observation(s) reflect(s) colligative properties? (i) A 0.5 m NaBr solution has a higher vapour pressure than a 0.5 m BaCl₂ solution at the same temperature (ii) Pure water freezes at the higher temperature than…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

Assertion: The water pouch of instant cold pack for treating athletic injuries breaks when squeezed and NH₄NO₃ dissolves lowering the temperature. Reason: Addition of non-volatile solute into solvent results into depr…

HARDMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

Assertion: If red blood cells were removed from the body and placed in pure water, pressure inside the cells increases. Reason: The concentration of salt content in the cells increases.

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

0.1 M NaCl and 0.05 M BaC₁₂ solutions are separated by a semipermeable membrane in a container. For this system, choose the correct answer. (AMU 2010)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

The mass of non-volatile solute of molar mass 40 g/mol that should be dissolved in 114 g of octane to lower its vapour pressure by 20% is (KCET 2012)

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

For an ideal solution, the correct option is: (2019) (a) mixV at constant T and P (b) mixH at constant T and P (c) mixG at constant T and P (d) mixS at constant T and P Ans. (b) Sol. For ideal solution, mix mix mix mi…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

0.2 molal acid HX ionises 20%. Kf for acid is 1.86 molality–1. Freezing point is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

If is degree of dissociation of Na₂SO₄, the van’t Hoff’s factor, i, used for calculating the molar mass is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

At o 25 C, the total pressure of an ideal solution obtained by mixing 3 moles of ‘A’ and 2 moles of ‘B’, is 184 torr. What is the vapour pressure (in torr) of pure ‘B’ at the same temperature? (Vapour pressure of pure…

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

0.01 M solution each of urea, common salt and Na₂SO₄ are taken, the ratio of depression of freezing point is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

Which of the following concentration terms is/are independent of temperature?

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

Van’t Hoff factor of Ca (NO₃)₂ is

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous solution, the change in freezing point of water ( Tf), when 0.01 mole of sodium sulphate is dissolved in 1 kg of water, …

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

A solution contains non-volatile solute of molecular mass M2. Which of the following can be used to calculate the molecular mass of solute in terms of osmotic pressure? (Punjab PMET 2007) (a) m M VRT (b) m RT M V (c) …

MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistrySolutions

Four solutions of K₂SO₄ with the following concentration 0.1 m, 0.01 m, 0.001 m and 0.0001 m SOLUTIONS are available. The maximum value of van’t Hoff factor, i, corresponds to

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