Chemistry Question Bank

Assertion (A) The reaction mentioned in Above ques. behaves as pseudo first order reaction. Reason (R) Change in the concentration of H2O is negligible.

Consider the following equation, H CH COOC H H O CH COOH C H OH -> t = 0 0.01 mol 10 mol 0 mol 0 mol t 0 mol 9.9 mol 0.01 mol 0.01 mol I.The concentration of water does not get altered much during the course of the…

What is true about pseudo first order reaction?

The value of rate constant of a pseudo first order reaction does not

Inversion of cane sugar in dilute acid is an example of

When one reactant is present in large excess in a chemical reaction between two substances, then the reaction is known as

10g of a radioactive isotope is reduced to 1.25 g in 12 yr. Calculate the half-life period of the isotope.

Half-life period of a first order reaction is 10 min. What percentage of the reaction will be completed in 100 min?

For a hypothetical reaction, A P -> the rate constant is 0.12 s-1. Which of the following statements(s) is/are correct, if [R]0 is the initial concentration? (a) 0 1/2 R t 0.12 12 x (b) 1/2 t 2 0.12 R (c) 1/2 0.69…

Suppose P is the initial concentration of reaction, then the half-life period of a reaction of nth order is proportional to (a) (b) (c) (d) Ans. (a) Sol. Relation between half-life period of a reaction and initial con…

A first order reaction is found to have a rate constant, k = 4.2 × 10-12 s-1. Find the half-life of the reaction

Which of the following statement(s) is/are true?

Expression for the half-life of zero order reaction is given as (a) 1/2 R t 2k (b) 0 1/2 R t 2k (c) 1/2 0.693 t k (d) 1/2 0.301 t k Ans. (b) Sol. 0 1/2 R t 2k For a zero order reaction.

Value of 1/2 t for first order reaction is (a) (b) (c) (d) Ans. (a) Sol. Value of t1/2 for first order reaction is 0.693 k

1/2 t for a zero order reaction is …(I)… proportional to the initial concentration of the reactants and …(II)… proportional to the rate constant. Choose the correct words to fill up the blanks (I) and (II) respectivel…

…A… of the reaction is the time in which the concentration of a reactant is reduced to one half of its initial concentration. Choose the appropriate word to fill ‘A’ from the options given below.

For a given reaction half life period was found to be directly proportional to the initial concentration of the reactant. The order is

What will be the half-life of the first order reaction for which the value of rate constant is 200 s–1?

The half-life period of a first order reaction is

In a first order reaction, reactant concentration ‘C’ varies with time ‘t’ as

In a first order reaction the concentration of reactant decreases from 800 mol/dm3 to 50 mol/dm3 in 2 × 104 sec. The rate constant of reaction in sec–1 is:

For a first order reaction, (A) -> product the concentration of A changes from 0.1 M to 0.025 M in40 min. The rate of reaction when the concentration of A is 0.01 M is

The correct expression for the rate constant for reactions of zero-order is

If ‘a’ is the initial concentration of the reactant, the time taken for completion of the reaction, if it is of zero-order, will be

For a general reaction X -> Y, the plot of conc. of X vs time is given in the figure. What is the order of the reaction and what are the units of rate constant?