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MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryAlkyl and Aryl Halides

Consider the following groups (I) — OCOCH3 (II) — OCH3 (III) — OSO2CH3 (IV) — OSO2CF3 The decreasing order of their leaving ability is

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryAlkyl and Aryl Halides

Among these nucleophiles, which of the following orders is correct for their nucleophilicity order in gas phase? - CH , NH , OH ,F (a) - CH >NH >OH >F (b) F OH NH CH (c) - OH >NH >F >CH

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryAlkyl and Aryl Halides

Θ Θ Θ Θ C H , N H ,O H,F Among these nucleophiles, which of the following orders is correct for their nucleophilicity in acetone? (a) Θ Θ Θ Θ CH N H O H> F (b) F OH NH CH (c) Θ Θ Θ Θ O H> N H F CH

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryAlkyl and Aryl Halides

Θ Θ Θ F, ,Br, I Cl Among these nucleophiles, which of the following orders is correct for their nucleophilicity order in DMF? (a) Θ Θ Θ F> >Br>I Cl (b) Θ Θ Θ Θ I>Br> >F Cl (c) Θ Θ Θ Θ I>Br>F>Cl

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryAlkyl and Aryl Halides

Θ Θ Θ Θ F,Cl,Br,I Among these nucleophiles, which of the following orders is correct for their nucleophilicity order in water? (a) Θ Θ Θ Θ F>Cl >Br>I (b) Θ Θ Θ Θ I>Br>Cl>F (c) Θ Θ Θ Θ I>Br>F>Cl (d) none of t…

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryAlkyl and Aryl Halides

Light C H Cl C H Cl HCl -> is an example of

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryAlkyl and Aryl Halides

When the concentration of alkyl halide is tripled and concentration of OH is reduced to half, the rate of SN2 reaction increased by:

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryAlkyl and Aryl Halides

Formation of free radical takes place with absorption of minimum energy in the formation of : (a) (b) (c) (d)

MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryAlkyl and Aryl Halides

The rate of SN1 reaction is fastest with: (a) (b) (c) CH Br CH NO2 Br (d)

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

The increasing order of the rate of HCN addition to compounds A-D is

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of a α-hydroxy acid. The carbonyl compound is

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

Arrange the following compounds in increasing order of their reactivity in nucleophilic addition reactions. Ethanal (I), Propanal (II), Propanone (III), Butanone (IV)

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

The reagent used in Gattermann Koch aldehyde synthesis is

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

Reduction of acetonitrile in presence of SnCl2/HCl, followed by hydrolysis gives :

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

What reagent is used in the Rosenmund reduction?

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

Catalyst used in Rosenmund reduction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

In the following reaction, product P is

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

On heating calcium acetate and calcium formate, the product formed is

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

Dry heating of calcium acetate gives

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

Consider the following statement Acetophenone can be prepared by (1) Oxidation of 1-phenyethanol (2) Reaction of 1-phenylethanol with methyl magnesiumbromide (3) Friedel Craft’s reaction of benzene with acetyl chlorid…

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

Acetone on distillation with conc. H2SO4 forms

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

The oxidation of toluene to benzaldehyde by chromyl chloride is called

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

Which one of the following can be oxidised to the corresponding carbonyl compound?

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

Methyl ethyl ketone is prepared by the oxidation of

MEDIUMMCQ SINGLEJEE Advanced ChemistryOrganic ChemistryAldehydes and ketones

The oxidation product of 2-propanol with hot conc. HNO3 is

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