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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction, N2 + 3H2 -> 2NH3, d NH dt = 2 x 10–4 mol L–1 s–1, the value of d H dt would be: (AIPMT 2009)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For an endothermic reaction, energy of activation is Ea and enthalpy of reaction of H (both of these in kJ/mol). Minimum value of Ea will be. (AIPMT 2010)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

During the kinetic study of the reaction, 2A B C D -> , following results were obtained: Run [A]/mol L–1 [B]/mol L–1 Initial rate of formation of D/mol L–1 min–1 I 0.1 0.1 6.0 10 x II 0.3 0.2 7.2 10 x III 0.3 0.4 2.…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of the reaction g g g NO Cl NOCl is given by the rate equation rate = k [NO]2 [Cl2]. The value of the rate constant can be increased by: (AIPMT 2010)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction [N2O5(g) -> 2NO2(g) + 1/2 O2(g)] the value of rate of disappearance of N2O5 is given as 6.25 × l0–3 mol L–1 s–1 The rate of formation of NO2 and O2 is given respectively as: (AIPMT 2010)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate law for the reaction, xA yB mP nQ -> is rate = . c d k A B What is the total order of the reaction? (Kerala CEE 2011)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The half-life of a substance in a certain enzyme- catalysed reaction is 138 s. The time required for the concentration of the substance to fall from 1.28 mg L– 1 to 0.04 mg L–1 is (AIPMT 2011)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The unit of rate constant for a zero-order reaction is. (AIPMT 2011 M)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Which one of the following statements for the order of a reaction is incorrect? (AIPMT 2011)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of the reaction 2N2O5 -> 4NO2 + O2 can be written in three ways: d N O k N O dt ' d NO k N O dt '' d O k N O dt The relationship between k and k' and between k and k" are; (AIPMT 2011 M)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Half-life of a reaction is found to be inversely proportional to the cube of initial concentration. The order of reaction is (AFMC 2012)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Activation energy (Ea) and rate constants (k1 and k2) of a chemical reaction at two different temperatures (T1 and T2) are related by: (AIPMT 2012) (a) ln a E k k R T T (b) ln a E k k R T T (c) ln a E …

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a zero-order reaction for every 10° rise of temperature, the rate is doubled. If the temperature is increased from 10°C to 100°C, the rate of the reaction will become: (AIPMT 2012)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a reaction, A + B -> Product, rate is doubled when the concentration of B is doubled, and rate increases by a factor of 8 when the concentrations of both the reactants (A and B) are doubled. Rate law for the reacti…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

A reaction having equal energies of activation for forward and reverse reaction has: (NEET 2013) (a) G (b) H (c) H G S (d) S

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

What is the activation energy for a reaction if its rate doubles when the temperature is raised from 20°C to 35°C? (R = 8.314 J mol–l K–l) (NEET Kar. 2013)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a reaction between A and B the order with respect to A is 2 and the order with respect to B is 3. The concentrations of both A and B are doubled, the rate will increase by a factor of: (NEET Kar. 2013)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

A reaction is 50% completed in 2 hours and 75% completed in 4 hours. The order of reaction is (NEET Kar. 2013)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The inversion of cane sugar is first order in [sugar] and proceeds with half-life of 600 minutes at pH = 4 for a given concentration of sugar. However, if pH = 5, the half-life changes to 60 minutes. The rate law expr…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The activation energy of a reaction can be determined from the slope of which of the following graphs? (NEET 2015)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

When initial concentration of a reactant is doubled in a reaction, its half-life period is not affected. The order of the reaction is: (NEET 2015)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate constant of the reaction A ->B is 0.6 × 10–3 mol L-1 second-1. If the concentration of A is 5 M then concentration of B after 20 minutes is: (NEET 2015 RS)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The decomposition of phosphine (PH3) on tungsten at low pressure is a first-order reaction. It is because the: (NEET II 2016)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The addition of a catalyst during a chemical reaction alters which of the following quantities? (NEET 2016)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of a first-order reaction is 0.04 mol L s at 10 seconds and 0.03 mol L s at 20 seconds after initiation of the reaction. The half-life period of the reaction is. (NEET 2016)

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