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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate constant of a reaction is given by ln k (sec–1) = 14.34 – (1.25 × 104)/T What will be the energy of activation?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The correct form of Arrhenius equation is (a) a E /RT k Ae (b) a RT/E k Ae (c) a E /RT k Ae (d) a RT/E k Ae

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In Arrhenius equation mentioned in Above Ques. ‘A’ is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

On the basis of Arrhenius equation mentioned in Above ques. consider the following statements. I.Ea is activation energy. II.Unit of Ea is J mol-1 III.R is gas constant. Which of these are true statements?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the Arrhenius equation, a E /RT k Ae , the factor a E /RT e corresponds to the

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

What will happen, on increasing the temperature or decreasing the activation energy (answer on the basis of Arrhenius equation)?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The temperature dependence of the rate constant k is expressed as a E RT k Ae When a plot between log k and 1/T is plotted we get the graph as shown. What is the value of slope in the graph? (a) a E RT (b) a E 2.303…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Energy of activation of an exothermic reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the graph shown below ‘I’ means

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The role of a catalyst is to change

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a 1st order reaction, the fraction of molecules at 450ºC having sufficient energy (or fraction of effective collisions) is 1.92 × 10–16. What is activation energy value of this reaction?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a reaction A ->B threshold energy of the reactant is 120 kJ mole–1 and the normal energy of the reactant is 20 kJ mole–1 what is the activation energy barrier of the reaction A ->B.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

What is the rate of reaction for a bimolecular elementary reaction?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Which of the following is a drawback of collision theory? a) Proper orientation b) High activation energy c) Hard spheres d) Have energy equal to or greater than the threshold energy

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rates of reactions increase with increase of temperature because

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

According to collision theory of reaction rates, the rate of reaction depends

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

If 60% of a first order reaction was completed in 60 minutes, 50% of the same reaction would be completed in approximately. (AIPMT 2007)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a first-order reaction A B -> , if k is rate constant and initial concentration of the reactant A is 0.5 M, then the half-life is. (AIPMT 2007)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The reaction of hydrogen and iodine monochloride is given as: 2 g g g 2 g H 2ICl 2HCl I -> The reaction is of first order with respect to 2 g H and g ICl following mechanisms were proposed. Mechanism A: 2 …

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate constants k1 and k2 for two different reactions are 1016. 2000/T e and 1015. 1000/T e , respectively. The temperature at which k1 = k2 is: (AIPMT 2008)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The bromination of acetone that occurs in acid solution is represented by this equation. CH COCH aq Br aq CH COCH Br aq H aq Br aq -> These kinetic data were obtained for given reaction concentrations. …

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction A + B -> products, it is observed that: (1) On doubling the initial concentration of A only, the rate of reaction is also doubled and (2) On doubling the initial concentrations of both A and B, there …

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

rate = k [A]1 [B]2

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Half life period of a first-order reaction is 1386 seconds. The specific rate constant of the reaction is: (AIPMT 2009) (a) 0.5 10 s x (b) 0.5 10 s x (c) 5.0 10 s x (d) 5.0 10 s x

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the reaction -> aq aq l l BrO Br H Br H O The rate of appearance of bromine (Br2) is related to rate of disappearance of bromide ions as following: (AIPMT 2009)

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