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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the graph, slope is (a) inst d R r dt (b) inst d R r d P (c) inst d P r dt (d) inst d P r dt Ans. (c) Sol. Slope ⇒ inst d P r dt

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

...A… depends upon the change in concentration of reactants or products and the time taken for that change to occur. Here, A is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The correct expression is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The square brackets in the expression Δ[R] = [R]2 – [R]1 are used to express …A… Here, A is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Speed of a reaction can be defined as

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The units of rate of reaction are

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Rate of a reaction

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of reaction is defined as

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a reaction R ⟶ P, the concentration of a reactant changes from 0.05 M to 0.04 M in 30 minutes. What will be the average rate of reaction in minutes?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction A + 2B ⟶ C, the rate of reaction at a given instant can be represented by (a) d[A] 1 d[B] d[C] dt 2 dt dt

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction. 2 HI ⟶ H2 + I2, the expression [ ] d HI dt represents

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a reaction 2HI ⟶ H2 + I2, the concentration of HI decreases from 0.5 mol L–1 to 0.4 mol L–1 in 10 minutes. What is the overall rate of reaction during this interval?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Consider the reaction, 2N O 4NO O . -> In the reaction NO2 is being formed at the rate of 0.0125 mol L–1 s–1. What is the rate of reaction at this time?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Chemical kinetics plays an important role in

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The correct expression for the rate constant for reactions of zero-order is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a first order reaction, (A) -> product the concentration of A changes from 0.1 M to 0.025 M in40 min. The rate of reaction when the concentration of A is 0.01 M is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a first order reaction the concentration of reactant decreases from 800 mol/dm3 to 50 mol/dm3 in 2 × 104 sec. The rate constant of reaction in sec–1 is:

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a first order reaction, reactant concentration ‘C’ varies with time ‘t’ as

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The half-life period of a first order reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

What will be the half-life of the first order reaction for which the value of rate constant is 200 s–1?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a given reaction half life period was found to be directly proportional to the initial concentration of the reactant. The order is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

…A… of the reaction is the time in which the concentration of a reactant is reduced to one half of its initial concentration. Choose the appropriate word to fill ‘A’ from the options given below.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

1/2 t for a zero order reaction is …(I)… proportional to the initial concentration of the reactants and …(II)… proportional to the rate constant. Choose the correct words to fill up the blanks (I) and (II) respectivel…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Value of 1/2 t for first order reaction is (a) (b) (c) (d) Ans. (a) Sol. Value of t1/2 for first order reaction is 0.693 k

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Expression for the half-life of zero order reaction is given as (a) 1/2 R t 2k (b) 0 1/2 R t 2k (c) 1/2 0.693 t k (d) 1/2 0.301 t k Ans. (b) Sol. 0 1/2 R t 2k For a zero order reaction.

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