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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a reaction X + Y ⟶ Z, rate[X]. What is (i) molecularity and (ii) order of reaction?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The following mechanism has been proposed for a reaction. 2P Q R S P Q T R Slow P T R fast -> -> -> The rate law expression for the reaction is (a) r k P Q (b) r k P (c) r k P T (d) r k P Q

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a reaction, 2NO 2H N 2H O, -> the possible mechanism is 2NO N O slow N O H N O H O -> fast N O H N H O -> What is the rate law and order of the reaction? (a) Rate = [N2O2], order =

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The chemical reaction, proceeds as O O [O] (fast) [O] O 2O -> (slow) The rate law expression will be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the sequence of reaction k k k A B C D -> -> -> k3 > k2 > k1, then the rate determining step of the reaction is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The overall rate of the reaction is controlled by the ______ step in a reaction. Choose the suitable word to fill the blank.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction 2A + B ⟶ D + E the following mechanism has been proposed : A + B ⟶ C + D (slow) A + C ⟶ E (fast) The rate law expression for the reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

…A… reactions involves a sequence of elementary reactions in the formation of product. Here, A refers to

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The reactions taking place in one step are called …A… reactions. Here, A is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

molL mol Ls s molL x A B C

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

molL s s molL x C. Second order reaction

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

molL molL s s molL x B. First order reaction

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Match the following Columns and choose the correct option from the codes given below. Column I (Reaction) Column II (Units of rate constant) A. Zero order reaction

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of formation of a dimer in a second order dimerisation reaction is 9.1 × 10–6 mol L–1 s–1 at 0.01 mol L–1 monomer concentration. What will be the rate constant for the reaction?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For which of the following, the units of rate constant and rate of the reaction are same?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The unit of the rate constant of nth order is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The equilibrium constant of reaction is 20.0 At equilibrium, the rate constant of forward reaction is 10.0. The rate constant for backward reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The unit of rate constant for a zero-order reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate law for a reaction between the substances P and Q is given by rate a b k P Q On doubling the concentration of P and reducing the concentration of Q to one-half, the ratio of the new rate to the earlier rate…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Statement I The rate law may not depend on the concentration of every reactants. Statements II With increase in temperature, the rate of reaction increases. Choose the correct option regarding above statements.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The conversion of molecules x to y follows second order kinetics. If concentration of x is increased to three times how will it affect the rate of formation of y ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Which of the following statement(s) is/are true? I.Rate law is an experimental fact while law of mass action is a theoretical proposal. II.Rate law is more informative than law of mass action for the development mecha…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction A + B ⟶ C + D, doubling the concentration of both the reactants increases the reaction rate by 8 times and doubling the initial concentration of only B simply doubles the reaction rate. The rate law f…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the reaction 2 A + B ⟶ Products, the order w.r.t. A is found to be one and w.r.t. B equal to 2. Concentration of A is doubled and that of B is halved, the rate of reaction will be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the gaseous reaction 2A + B ⟶ C + D, the rate is given by k [A] [B]. The volume of the container containing the reaction mixture is suddenly reduced to one fourth of its original volume. with respect to the origin…

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