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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The correct order of acid strength is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Cl – is the conjugate base of

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The conjugate base of NH2 – is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

A weak acid, HA has a Ka of 1.00 10 x . If 0.100 mole of this acid is dissolved in 1 L of water, the percentage of acid dissociated at equilibrium is closest to

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The  solubility  of  CaCO3  is  7  mg/L.  Calculate  the solubility product of BaCO3 from this information and from  the  fact that  when  Na2CO3  is added slowly  to  a solution  containing  equimolar  concentration …

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The solubility of AgCl is maximum in

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The solubility of LiOH in a solution with pH = 8 is (Ksp = 1.8 × 10–12)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion (A): pH of HCl solution is less than that of acetic acid of the same concentration. Reason (R):  In  equimolar  solutions,  the  number  of titrable protons present in HCl in less than that present in acetic…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: If HA and HB are two weak non-basic acids with Ka(HA)  < Kb(HB), then, the aqueous solution  of NaA will have higher pH than pH of aqueous solution of NaB of same concentration. Reason: Conjugate base of  a…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH3COOAg is diluted, then its degree of hydrolysis increases. Reason:  Silver  acetate  is  the  salt  of  weak  acid  and weak base; its degree of hydrolysis does not depend on th…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: When aqueous, solution of CH3COONH4 is diluted, then its degree of hydrolysis increases. Reason:  Ammonium  acetate  is  the  salt  of  weak  acid and  weak  base;  its  degree  of  hydrolysis  does  not de…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: Aqueous  solution of  ammonium  carbonate is basic. Reason: Acidic or Basic nature of a salt solution of a salt  of  weak  acid  and  weak  base  depends  on  Ka  and Kb of the acid and base forming it.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: If a K  of HA is 10–3 and a K  of HB is 10 at 25ºC, pH of an aqueous solution of HB will be one unit greater than pH of equimolar solution of HA. Reason:  For  weak  acids,  both  concentration  and ionizat…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: pH of 10–8 M HCl lies between 6 and 7. Reason:  For  very  dilute  solutions  of  acids,  H+  ion contribution from water is also taken into consideration.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: pH  of  water  increases  with  an  increase  in temperature. Reason: Kw  of  water  increases  with  increase  in temperature.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion: Addition  of  HCl(aq.)  to  HCOOH(aq.) decreases the ionization of HCOOH. Reason:  Common  ion  effect  of  H+  ion,  reduces  the ionization of HCOOH.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Assertion (A): H2SO4 acts as a base in the presence of HClO4. Reason (R): Perchloric  acid  is  stronger  acid  than H2SO4.

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The solubility products of MA, MB, MC and MD are 1.8 × 10–10, 4 × 10–3, 4 × 10–8 and 6 × 10–5 respectively. If  a  0.01  M  solution  of  MX  is  added  dropwise  to  a mixture containing A–, B–, C– and D– ions then t…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Ksp of Mg (OH)2 is 1 × 10–12. 0.01 M Mg (OH)2 will be precipitating at the limiting pH :

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Calculate  the  concentration  of  H+  ion  in  mol/L  of 0.010M solution of NH4Cl? (Kb = 1.8 × 10–6)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

The correct order of increasing [H3O+] in the following aqueous solution is:

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

H S aq H aq HS aq ;K 9.5 10 x HS aq H aq S aq ;K 1.0 10 x Given  the  equilibrium  constants  provided  what  is  the equilibrium constant for the reaction: S (aq) 2H (aq) H S(aq) K = ?

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

How  many  milliliters  (mL)  of  a  0.0500  M  NaOH  (a strong  base)  solution  should  be  added  to  1.00  L  of 0.100 M H3PO4, solution to produce a buffer of pH = 2.00 ? For H3PO4, a K = 6.67 × 10–3 Given: H P…

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

How many milliliters of 0.250 M NH4Cl would have to be  added  to  450  mL  of  0.350  M  KOH  in  order  to produce a buffer solution with a pH of 9.10? (Kb(NH3) = 1.8 × 10–5)

HARDMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibrium

Which  pair  of  reagents,  mixed  in  the  appropriate proportion, could make a buffer in pH 3-4 range ?

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