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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Order of a chemical reaction is defined as the

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of reaction A + B + C ⟶ Products is given by Rate = k [A]1/2 [B]1/3 [C] The order of the reaction is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Order of a reaction can be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The reactions of higher order are rare because

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate constant of a reaction is 2.5 × 10–2 minutes–1. The order of the reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of a reaction 2X + Y ⟶ Products is given by d[Y] dt = k [X]2 [Y] if X is present in large excess, the order of the reaction is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction CH3COCH3 + I2 H ->Products, the rate is governed by the expression dx k dt [Acetone] [H+] The order w.r.t. iodine is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate law expression for the hypothetical reaction 2 A + 3 B ⟶ 2 C is = k [A] [B]2 The order of reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a single step reaction; A + 2 B ⟶ Products, the molecularity is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Which one of the following statements is incorrect about the molecularity of a reaction?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a reaction X + Y ⟶ Z, rate[X]. What is (i) molecularity and (ii) order of reaction?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The following mechanism has been proposed for a reaction. 2P Q R S P Q T R Slow P T R fast -> -> -> The rate law expression for the reaction is (a) r k P Q (b) r k P (c) r k P T (d) r k P Q

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a reaction, 2NO 2H N 2H O, -> the possible mechanism is 2NO N O slow N O H N O H O -> fast N O H N H O -> What is the rate law and order of the reaction? (a) Rate = [N2O2], order =

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The chemical reaction, proceeds as O O [O] (fast) [O] O 2O -> (slow) The rate law expression will be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In the sequence of reaction k k k A B C D -> -> -> k3 > k2 > k1, then the rate determining step of the reaction is :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The overall rate of the reaction is controlled by the ______ step in a reaction. Choose the suitable word to fill the blank.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the reaction 2A + B ⟶ D + E the following mechanism has been proposed : A + B ⟶ C + D (slow) A + C ⟶ E (fast) The rate law expression for the reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

…A… reactions involves a sequence of elementary reactions in the formation of product. Here, A refers to

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The reactions taking place in one step are called …A… reactions. Here, A is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

molL mol Ls s molL x A B C

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

molL s s molL x C. Second order reaction

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

molL molL s s molL x B. First order reaction

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Match the following Columns and choose the correct option from the codes given below. Column I (Reaction) Column II (Units of rate constant) A. Zero order reaction

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate of formation of a dimer in a second order dimerisation reaction is 9.1 × 10–6 mol L–1 s–1 at 0.01 mol L–1 monomer concentration. What will be the rate constant for the reaction?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For which of the following, the units of rate constant and rate of the reaction are same?

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