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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a hypothetical reaction, A P -> the rate constant is 0.12 s-1. Which of the following statements(s) is/are correct, if [R]0 is the initial concentration? (a) 0 1/2 R t 0.12 12 x (b) 1/2 t 2 0.12 R (c) 1/2 0.69…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Suppose P is the initial concentration of reaction, then the half-life period of a reaction of nth order is proportional to (a) (b) (c) (d) Ans. (a) Sol. Relation between half-life period of a reaction and initial con…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

A first order reaction is found to have a rate constant, k = 4.2 × 10-12 s-1. Find the half-life of the reaction

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Which of the following statement(s) is/are true?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Expression for the half-life of zero order reaction is given as (a) 1/2 R t 2k (b) 0 1/2 R t 2k (c) 1/2 0.693 t k (d) 1/2 0.301 t k Ans. (b) Sol. 0 1/2 R t 2k For a zero order reaction.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Value of 1/2 t for first order reaction is (a) (b) (c) (d) Ans. (a) Sol. Value of t1/2 for first order reaction is 0.693 k

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

1/2 t for a zero order reaction is …(I)… proportional to the initial concentration of the reactants and …(II)… proportional to the rate constant. Choose the correct words to fill up the blanks (I) and (II) respectivel…

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

…A… of the reaction is the time in which the concentration of a reactant is reduced to one half of its initial concentration. Choose the appropriate word to fill ‘A’ from the options given below.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a given reaction half life period was found to be directly proportional to the initial concentration of the reactant. The order is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

What will be the half-life of the first order reaction for which the value of rate constant is 200 s–1?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The half-life period of a first order reaction is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a first order reaction, reactant concentration ‘C’ varies with time ‘t’ as

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

In a first order reaction the concentration of reactant decreases from 800 mol/dm3 to 50 mol/dm3 in 2 × 104 sec. The rate constant of reaction in sec–1 is:

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a first order reaction, (A) -> product the concentration of A changes from 0.1 M to 0.025 M in40 min. The rate of reaction when the concentration of A is 0.01 M is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The correct expression for the rate constant for reactions of zero-order is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

If ‘a’ is the initial concentration of the reactant, the time taken for completion of the reaction, if it is of zero-order, will be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For a general reaction X -> Y, the plot of conc. of X vs time is given in the figure. What is the order of the reaction and what are the units of rate constant?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate constant of a first order reaction is 15 ×10-3 s–1. How long will 5.0 g of this reactant take to reduce to 3.0 g?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

1.386 hours are required for the disappearance of 75% of a reactant of first-order reaction. What is the rate constant of the reaction?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

For the first order reaction A ⟶ Products, which one of the following is the correct plot of log [A] versus time? (a) (b) (c) (d)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The rate constant for a zero order reaction is 2 × 10–2 mol L–1 sec–1. If the concentration of the reactant after 25 sec is 0.5 M, the initial concentration must have been

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

…A… dependence of rate is called differential rate equation. Choose the suitable word to replace A.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Assertion (A) Molecularity of a reaction can have a fractional value. Reason (R) Order of a reaction can have a fractional value.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

Assertion (A) The reaction, H Br 2HBr -> has a molecularity of two. Reason (R) Order of reaction is 3/2.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryChemical kinetics

The reaction, 2N O 4NO O is

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