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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The compressibility of a gas is less than unity at STP. Therefore

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

At high pressure, all the gases have

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

Dominance of strong repulsive force among the molecules of the gas (Z = compressibility factor)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The compressibility factor (Z) is defined as (a) real ideal V V (b) P Z nRT (c) ideal real V V (d) nRT Z PV

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

In Van der Waal’s equation of state for a non-ideal gas, the term that accounts for intermolecular forces is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The value of Van der Waal’s constant ‘a’ for the gases O2, N2, NH3 and CH4 are 1.360, 1.390, 4.170 and 2.253L2 atm mol–2 respectively. The gas which can most easily be liquified is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

For one mole of a vander Waals’ gas when b = 0 and T = 300 K, the PV vs. 1/V plot is shown below. The value of the van der Waals’ constant a (atm L mol–2)

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The term that corrects for the attractive forces present in a real gas in the van der Waals’ equation is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

In van der Waals equation of state of the gas law, the constant ‘b’ is a measure of

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The units of the van der Waal’s constant ‘b’ are

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

Van der Waals constants ‘a’ and ‘b’ are related with..... respectively.

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The units of the van der Waal’s constant ‘a’ are

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

a and b are van der Waals constants for gases. Chlorine is more easily liquefied than ethane because

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

A gas will approach ideal behaviour at

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

Two separate bulbs contain ideal gases A and B. The density of gas A is twice that of gas B. The molecular mass of A is half that of gas B. The two gases are at the same temperature. The ratio of the pressure of A to …

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

In case of hydrogen and helium, the van der Waal’s forces are

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

Any gas shows maximum deviation from ideal gas at

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

For a gas deviation from ideal behaviour is maximum at :

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

A gas is said to behave like an ideal gas when the relation PV/T = constant. When do you expect a real gas to behave like an ideal gas ?

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The pressure of real gases is less than that of ideal gas because of

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The ratio of root mean square velocity to average velocity of a gas molecule at a particular temperature is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The average velocity of an ideal gas molecule at 27ºC is 0.3 m/s. The average velocity at 927º C will be

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

At constant volume, for a fixed number of moles of a gas the pressure of the gas increases with rise of temperature due to

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The ratio between the root mean square speed of H2 at 50K and that of O2 at 800 K is

MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryGaseous state

The r.m.s. velocity of hydrogen is 7 time the r.m.s. velocity of nitrogen. If T is the temperature of the gas,

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