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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Pick out the wrong statement

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

G is the net energy available to do useful work and is a measure of free energy. If a reaction has positive enthalpy change and positive entropy change, under what conditions will the reaction be spontaneous?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

2 moles of ideal gas at 27°C temperature is expanded reversibly from 2 lit. to 20 lit. find entropy change. (R = 2 cal/mol K)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Cell reaction is spontaneous when (a) G is negative (b) G is positive (c) red G is positive (d) red G is negative

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Enthalpy change for the reaction, 4H(g)  → 2H₂(g) is – 869.5 kJ. The dissociation energy of H–H bond is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Gaseous system is placed with pressure P₁, volume V₁ and  temperature  T1,  it  has  undergone  thermodynamic changes where temperature is remaining constant, it is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Based on the first law of thermodynamics, which one of the following is correct?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

U q w , is mathematical expression for

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

According to the first law of thermodynamics, U q w . In special cases the statement can be expressed in different ways. Which of the following is not a correct expression?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Two moles of Helium gas undergo a reversible cyclic process as shown in figure. Assuming gas to be ideal. What is the work done for the process C to D?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

E is always positive, when

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

An ideal gas is taken around the cycle ABCA as shown in P-V diagram The net work done by the gas during the cycle is equal to:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

An ideal gas receives 10 J of heat in a reversible isothermal expansion. Then the work done by the gas:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas is initially at 0°C and 1 atm pressure. If it absorbs 1000 cal heat during a reversible isothermal expansion, what will be its final volume?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The maximum work obtained by an isothermal reversible expansion of 1 mole of an ideal gas at 27°C from 2.24 to 22.4 L is (R = 2 cal)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

16g of oxygen gas expands isothermally and reversibly at 300 K from 10 dm3 to 100 dm3. The work done is (in J)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The work done during the expansion of a gas from a volume of 4dm3 to 6 dm3 against a constant external pressure of 3 atm is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

1 mole of NH₃ gas at 27°C is expanded in reversible adiabatic condition to make volume 8 times (γ = 1.33). Final temperature and work done by the gas respectively are:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

One mole of an ideal gas expands reversibly and adiabatically from a temperature of 27°C. If the work done during the process is 3 kJ, then final temperature of the gas is:(CV = 20 J/K)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Which of the following expressions regarding entropy is not correct? (a) system q S T (b) system total surrounding S S S (c) final initial S S S (d) total system surrounding S S S

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Read the following statements regarding spontaneity of a process and mark the appropriate choice. (i)   When enthalpy factor is absent then randomness factor decides spontaneity of a process. (ii) When randomness fact…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

Unit of entropy is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

In which case change in entropy is negative?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

When one mole of an ideal gas is compressed to half of its initial volume and simultaneously heated to twice its initial temperature, the change in entropy of gas (∆S) is :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryThermodynamics and Thermochemistry

The following data is known about the melting of a compound AB. ∆H = 9.2 kJ mol–1. ∆S = 0.008 kJ K–1mol–1. Its melting point is :

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