Chemistry Question Bank

For a reaction pA + qB ⟶ products, the rate law expression is r = k [A]m [B]n then

Which of the following statement is/are correct? (a) A catalyst is used in the rate determining step of a mechanism, but then is formed again in some subsequent step so that there is no change in the concentration of …

Mark the correct statement.

The solid-vapour equilibrium can be represented as I. I2 (solid) I2 (vapour) II. Camphor (solid) Camphor (vapour) III. NH4Cl (solid) NH4Cl (vapour) Point out the correct option(s).

Chemical equilibria are important in numerous … (X) … and …. (Y) … processes. Here, (X) and (Y) refer to

For the reaction : N (g) O (g) NO(g) If pressure is increased by reducing the volume of the container, then

Au(s) Au(l) Above equilibrium is favoured at

When a gas “X” is dissolved in water, the heat is evolved. Then solubility of ‘X’ will increase at

If for a particular reversible reaction : Kc = 57 at 355ºC and Kc = 69 at 450º, then

For exothermic reaction is Sº < 0, then the sketch of log K vs 1/T may be (a) (b) (c) (d)

If standard heat of dissociation of PCl5 is 230 cal, then slope of the graph of log k vs 1 T is

Assertion : For PCl5(g) PCl3(g) + Cl2(g). If more Cl2 is added, the equilibrium will shift in backward direction hence equilibrium constant will decrease. Reason : Addition of inert gas to the equilibrium mixture at…

Assertion :A catalyst does not influence the value of equilibrium constant. Reason : Catalyst influence the rate of both forward and backward reactions equally.

Assertion : The addition of an inert gas under constant volume condition cause the total pressure of the system to increase. This would thus lower the degree of dissociation of PCl5. Reason : Addition of inert gas at …

Assertion : Addition of an inert gas at constant pressure equilibrium will support the dissociation of PCl5 at the same temperature. Reason : The addition of an inert gas will tend to increase the total pressure.

Assertion : For the reaction g g g g A B C D at the given temperature, there will be no effect by addition of inert gas either at constant pressure or at constant volume. Reason : For the reaction where n = 0,…

Assertion : Kp is equal to Kc for the following reaction: N2(g) + O2(g) 2NO(g) Reason : Kp and Kc are interrelated by the following equation : g n p c K K (RT) ng = Number of gaseous moles of products – Number of g…

Assertion : If the equation for a reaction is reversed, the equilibrium constant is inverted and if the equation is multiplied by 2, the equilibrium constant is squared. Reason : The numerical value of equilibrium con…

Assertion : For a reversible reaction, Gibbs’ free energy is zero at equilibrium. Reason : As reaction approaches equilibrium, Gibbs’ free energy decreases.

Assertion : If some PCl5(g) containing labelled phosphorus P31 is added to a system with following equilibrium, after sometime the system was found to contain radioactive PCl3. PCl (g) PCl (g) Cl (g) Reason : Chemic…

Assertion : For a reaction at equilibrium, the free energy for the reaction is minimum. Reason : The free energy for both reactants and products decreases and become equal.

In a 1.0 L aqueous solution when the reaction (aq) (s) 2 Ag Cu (aq) (s) Cu 2 Ag reaches equilibrium, [Cu2+] = x M and [Ag+] = y M. If the volume of solution is doubled by adding water, then at equilibrium : (a) x …

Variation of log K with 1 T is shown by the following graph. Hº for the reaction will be :

In each of the following, total pressure set-up at equilibrium is assumed to be equal and is one atm with equilibrium constants KP given : I :CaCO3 (s) CaO (s) + CO2 (g), K1 II : NH4HS (s) NH3 (g) + H2S (g), K2 III :…

For the chemical equilibrium, CaCO (s) CaO(s) CO (g) , Hº can be determined from which one of the following graphs ? (a) (b) (c) (d)