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HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Assertion (A): The order of a reaction can have fractional value. Reason (R): The order of a reaction cannot be written from balanced equation of a reaction.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Assertion (A): If the activation energy of a reaction is zero, temperature will have no effect on the rate constant. Reason (R): Lower the activation energy, faster is the reaction.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The instantaneous rate of reaction at the beginning of the reaction is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

The reaction, 2N O 4NO O is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Four reactions are given below. Which one of them is of zero order? (a) PCl PCl Cl -> (b) 2FeCl SnCl 2FeCl SnCl -> (c) H Cl 2HCl -> (d) N O 2NO O -> Ans. (c) Sol. The order of all photochemical reactions is zero …

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Choose the correct answer out of the following choices. Assertion (A) Order and molecularity are different. Reason (R) Order can be determined experimentally and molecularity is the sum of the stoichiometric coefficie…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Choose the correct answer out of the following choices. Assertion (A) Some zero order reactions may have order in fractions. Reason (R) Order cannot be determined from balanced chemical equation.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Which of the following statement(s) is/are correct about order of a reaction? I.The order of a reaction can be a fractional number. II.Order of a reaction is experimentally determined quantity. III.The order of a reac…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Consider the data given below for a hypothetical reactions M N -> Times(s) Rate of reaction (mol L-1 s-1) 4.20 × 10-4 4.20 × 10-4 4.20 × 10-4 4.20 × 10-4 4.18 × 10-4 For the above data, the order of reaction is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Statement I For a complex reaction, order is given by the slowest step of the reaction. Statement II Molecularity of the slowest step is same as the order of the overall reaction. Which of these statement(s) is/are tr…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

2NO O 2NO ->

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

2HI H I -> C. Trimolecula r

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

NH NO N 2H O -> B. Bimolecular

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

NH NO N 2H O -> A B C (a) (b) (c) (d)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

2NO O 2NO -> C. Trimolecular

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

2HI H I -> B. Bimolecular

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Match the following Columns and choose the correct option from the codes given below. Column I (Type of reaction) Column II (Example) A. Unimolecular

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

For a reaction, A B -> product, the rate law is given by, 1/2 r k A B . what is the order of the reaction?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

For the rate expression rate 3/2 k A B the overall order of a reaction is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

In the presence of acid, the initial concentration of cane-sugar was reduced from 0.2 M to 0.1 M in 5 hrs and to 0.05 M in 10 hrs. The reaction must be of

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Which of the following statements is false?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

For a simple reaction, 2P Q R S, -> molecularity will be

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Find the order of the reaction whose rate constant is 2.5 × 10-2 min-1

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Identify the incorrect statement.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryChemical kinetics

Decomposition of ammonium nitrite is an example of

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