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HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Assertion:1-butene on reaction with HBr in the presence of a peroxide produces 1-bromobutane. Reason: It involves the formation of a primary radical.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Assertion: The addition of HBr on 2-butene gives two isomeric products. Reason: Addition of HBr on 2-butene follows Markownikoff’s rule.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

For the formation of toluene by Friedal Craft reaction, reactants used in presence of anhydrous AlCl3 are

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Select the true statement about benzene amongst the following

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Which among the following groups when attached to benzene ring will direct the incoming electrophile predominantly to the meta position? (I) – CH3 (II) –CH2Cl (III) (IV) –CCl3 (V) –NHCOCH3

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Product The main product is (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Ethylbenzene with bromine in presence of FeBr3, predominantly gives (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

An aromatic compound ‘X’ with molecular formula C8H10 on nitration gives one mononitro derivative and three dinitro derivatives. Compound ‘X’ would be

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

The compound X in the reaction, (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Which of the following sequence of reactions (reagents) can be used for the conversion of C6H5CH2CH3 into C6H5CH=CH2?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Which is not aromatic compound? _

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Among the following, the aromatic comopound is: (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Reduction of 2-butyne with sodium in liquid ammonia gives predominantly :

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

The product A, is (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Acetylenic hydrogens are acidic because

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

CH CH CH

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

A hydrocarbon A on chlorination gives B which on heating with alcoholic potassium hydroxide changes into another hydrocarbon C. The latter decolourises Baeyer's reagent and on ozonolysis forms formaldehyde only. A is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

In the presence of platinum catalyst, hydrocarbon A adds hydrogen to form n-hexane. When hydrogen bromide is added to A instead of hydrogen, only a single bromo compound Is formed. Which of the following is A? (a) CH …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

When 3, 3-dimethyl 2-butanol is heated with H2SO4, the major product obtained is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

When hydrochloric acid gas is treated with propene in presence of benzoyl peroxide, it gives.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

The reagent is Reagent R CH CCl R R C C R ->

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Consider the following statements : A hydrocarbon of molecular formula C5H10 is a I. monosubstituted alkene II. disubstituted alkene III. trisubstituted alkene Which of the following statement(s) is(are) correct?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Which one of the following reactions is expected to readily give a hydrocarbon product in good yields? (a) Electrolytic RCOOK oxidation -> (b) Br2 RCOO Ag -> (c) Br2 RCOO Ag ->

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

In the given reactions : Br Na,ether Na,ether (i)CH Br X Y Z hv Br NaOH NaOH (ii)CH COOH X Y Z CaO hv -> -> -> -> -> -> Identify X, Y and Z. X Y Z

HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbons

Match the column I with column II and mark the appropriate choice. Column I Column II (A) n-butane 2-methylpropane (i) Free radical substitution (B) hv CH Cl CH Cl -> (ii) Wurtz reaction (C) RCOONa + soda lime RH (…

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