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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

(iii) mix S for an ideal solution.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The mixture that forms maximum boiling azeotrope is: (NEET 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The vapour pressure of pure CHC₁₃ and CH₂C₁₂ are 200 and 41.5 atm respectively. The weight of CHC₁₃ and CH₂C₁₂ are respectively 11.9 g and 17 g. The vapour pressure of solution will be (AllMS 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The mixture which shows positive deviation from Raoult’s law is: (NEET 2020)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The freezing point depression constant f K of benzene is 5.12 K kg mol-1. The freezing point depression for the solution of molality 0.078 m containing a non- electrolyte solute in benzene is (rounded off upto two dec…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

A solution contains non-volatile solute of molecular mass M2. Which of the following can be used to calculate the molecular mass of solute in terms of osmotic pressure? (Punjab PMET 2007) (a) m M VRT (b) m RT M V (c) …

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The normality of 10% H₂SO₄ solution (d = 1.1g/cm3) is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Calculate the molarity of H₂SO₄ solution if the normality of H₂SO₄ Solution is 0.4 N.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

At a particular temperature, the vapour pressures of two liquids A and B are respectively 120 and 180 mm of Hg respectively. If 2 moles of A and 3 moles of B are mixed to form an ideal solution, the vapour pressure of…

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The latent heat of vaporisation of water is 9700 cal/mole and if the b.p. is 100 °C, the ebullioscopic constant of water is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

A solution of urea (mol. mass 56 g mol-1) boils at 100.18 °C at the atmospheric pressure. If Kf and Kb for water are 1.86 and 0.512 K kg mol-1 respectively, the above solution will freeze at

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

An aqueous solution of NaCl shows the depression of freezing point of water equal to 0.372 K. The boiling point of BaCl₂ solution of same molality will be [Kf (H₂O)= 1.86 K kg mol–1; Kb(H₂O) = 0.52 K kg mol–1]

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

An aqueous solution of NaCl freezes at –0.186 °C. Given that 0.512 H O b K K kg mol and 1.86 H O f K K kg mol , the elevation in boiling point of this solution is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Assertion: 1.575g H₂C₂O₄.2H₂O in 250 mL solution makes it 0.1 N. Reason : H₂C₂O₄.2H₂O is a dihydrate organic acid.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

A solution of sucrose (molar mass = 342g mol -l) has been prepared by dissolving 68.5g of sucrose in 1000g of water. The freezing point of the solution obtained will be (Kf for water = 1.86 K Kg mol-l) (AFMC 2010) (a)…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Of the following 0.10 m aqueous solutions, which one will exhibit the largest freezing point depression? (AIPMT 2014)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

If sodium sulphate is considered to be completely dissociated into cations and anions in aqueous solution, the change in freezing point of water ( Tf), when 0.01 mole of sodium sulphate is dissolved in 1 kg of water, …

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

0.01 M solution each of urea, common salt and Na₂SO₄ are taken, the ratio of depression of freezing point is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

If is degree of dissociation of Na₂SO₄, the van’t Hoff’s factor, i, used for calculating the molar mass is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Which of the following aqueous solutions has the highest boiling point?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Assertion: The molecular weight of acetic acid determined by depression in freezing point method in benzene and water was found to be different. Reason: Water is polar, and benzene is nonpolar.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Which of the following pair of solutions are expected to be isotonic at the same temperature?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

Van’t Hoff factor of Ca (NO₃)₂ is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

0.2 molal acid HX ionises 20%. Kf for acid is 1.86 molality–1. Freezing point is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistrySolutions

The freezing point (in ºC) of solution containing 0.04g of AlCl₃ (mol. wt. 133) in 100g of water (Kf = 1.86 K kg mol–1) is

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