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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

The arrangement of (CH3)3C—, (CH3)2CH—, CH3CH2 — when attached to benzene or unsaturated group in increasing order of inductive effect is GENERAL ORGANIC CHEMISTRY

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Which of these groups has –I effect?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Inductive effect of Cl atom operates in (a) CH CH CH Cl (b) CH CH CH CH Cl (c)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

F COOCH COCl I II III Which of these groups has –I effect?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Negative inductive effect is shown by

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Which among the following free radicals is most stable? (a) (b) (c) (d) GENERAL ORGANIC CHEMISTRY

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Arrange the following free radicals in order of decreasing stability. Methyl (I), Vinyl (II), Allyl (III), Benzyl (IV)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Assertion: Tertiary carbocations are generally formed more easily than primary carbocations. Reason: Hyperconjugation as well as inductive effect due to additional alkyl groups stabilize tertiary carbocations.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Assertion: Tropylium cation is more stable than Reason: It is stabilized by both resonance effect and inductive effect.

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Which carbocation is the most stabilized? (a) (b) GENERAL ORGANIC CHEMISTRY (c) (d)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Which of the following is the most stabilized carbocation? (a) (b) (c) (d)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

What is the decreasing order of stability (most stable ->least stable) of the following carbocations?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Rearrangement in this carbocation will produce (a) (b)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Rearrangement in this carbocation will produce (a) GENERAL ORGANIC CHEMISTRY (b)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Which of the following carbocations will be most stable? (a) Ph C (b) CH CH (c) (CH ) CH (d) CH CH CH

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Most stable carbonium ion is (a) C H (b) (CH ) C (c) (C H ) C (d) C H CH

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Which of the following statements is correct about methyl group?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Consider the following carbocations, (I) C H CH (II) C H CH CH (III) C H CHCH (IV) C H C CH The correct sequence of the stability of these is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Which of the following orders is correct for the stability of these carbanions ?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Consider the following carbocations (I) Cl3C+ (II) Cl2CH+ (III) ClCH (IV) CH The stability sequence follows the order

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Due to the presence of an unpaired electron, free radicals are

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Which of the following orders is correct for no-bond- resonance energy of these radicals ?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

CH CH CH CH HC C III II I Which of the following orders is correct for the stability of these carbanions ?

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

Most stable carbocation is (a) (b) (c) (d)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryGOC

What is the correct order of stability of the given cations: CH3CHCHCH3 H3C OH 3-methyl-2-butanol 3 2 1 GENERAL ORGANIC CHEMISTRY

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