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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

A coordination compound of cobalt has the molecular formula containing five ammonia molecules, one nitro group and two chlorine atoms for one cobalt atom. One mole of this compound produces three moles of ions in an a…

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The number of ions formed from a molecule of potassium ferrocyanide in aqueous solution is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Cr3+ form four complexes with four different ligands which are [Cr(Cl)6]3–, [Cr(H2O)6]3+, [Cr(NH3)6]3+ and [Cr(CN)6]3–. The order of CFSE (0) in these complexes is in the order :

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The magnitude of crystal field stabilization energy in tetrahedral complexes (CFSE of t ) is considerably less than that in the octahedral field because

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The crystal field splitting energy for octahedral ( ) and tetrahedral ( t ) complexes is related as (a) t (b) t (c) t (d) t

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Assign the hybridization, shape and magnetic moment of K3[Cu(CN)4]:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

[Cr(H2O)6]Cl3 (atomic number of Cr = 24) has a magnetic moment of 3.83 B.M. The correct distribution of 3d electrons in the chromium present in the complex is:

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among the following, the compound that is both paramagnetic and coloured is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The compound having tetrahedral geometry is

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following is the correct order of increasing field strength of ligands to form coordination compounds? (NEET 2020)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

What is the correct electronic configuration of the central atom in K4[Fe(CN)6] based on crystal field theory? (NEET UG 2019)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Iron carbonyl, Fe(CO)5 is (NEET 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which one of the following ions exhibits d-d transition and paramagnetism as well? (NEET 2018) (a) 2- Cr O (b) - MnO (c) 2- CrO (d) 2- MnO

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The type of isomerism shown by the complex [CoCl2(en)2] is (NEET 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The geometry and magnetic behaviour of the complex [Ni(CO)4] are (NEET 2018)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The correct order of the stoichiometries of AgCl formed when AgNO3 in excess is treated with the complexes: CoCl36NH3, CoCl35NH3, CoCl34NH3 respectively is (NEET 2017)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

An example of a sigma bonded organometallic compound is (NEET 2017)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following has longest C-O bond length? (Free C-O bond length is CO is 1.128Å.) (NEET 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Jahn-Teller effect is not observed in high spin complexes of (NEET 2016)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Which of the following species contains equal number of -and -bonds? (AIPMT 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Cobalt (III) chloride forms several octahedral complexes with ammonia. Which of the following will not give a test of chloride ions with silver nitrate at 25ºC? (AIPMT 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The name of complex ion, [Fe(CN)6] 3– is (NEET 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Number of possible isomers for the complex [Co(en)2Cl2] Cl will be (en = ethylenediamine) (AIPMT 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

The sum of coordination number and oxidation number of the metal M in the complex [M(en)2(C2O4)]Cl (where en is ethylenediamine) is (AIPMT 2015)

MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCoordination compounds

Among the following complexes the one which shows zero crystal field stabilization energy (CFSE) is (AIPMT 2014)

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