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MEDIUMMCQ SINGLEJEE Mains ChemistryInorganic ChemistryMetallurgyVan-Arkel process

In the equation, 4M+8CN– + 2H2O + O2-> 4 [M(CN)2]– + 4OH–, the metal M is

A.Copper
B.Iron
C.Gold✓ Correct
D.Zinc
Explanation

Cyanide process is carried out to obtain less reactive metals like gold and silver. The impure metal is treated with NaCN solution in presence of air. The metal then forms a soluble complex. The reaction is- - - - 2 2 2 4Au+8CN +2H O+O 4[M(CN) ] +4OH -> Extraction of Iron and Copper 52. Which ore contains both iron and copper? (a) Cuprite (b) Chalcocite (c) Chalcopyrite (d) Malachite The molecular formula of cuprite is 2 Cu O . The molecular formula of chalcocite is 2 Cu S . The molecular formula of chalcopyrite is 2 CuFeS , and the molecular formula of malachite is 2 3 Cu(OH) .CuCO . So,

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