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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryIonic equilibriumPrevious Year Questions

Following solutions were prepared by mixing different volumes of NaOH and HCl of different concentrations. (NEET 2018) (A) M M 60mL HCl+40mL NaOH (B) M M 55mL HCl + 45mL NaOH (C) M M 75mL HCl + 25mL NaOH (D) M M 100mL HCl +100mL NaOH pH of which one of them will be equal to 1?

A.A
B.D
C.B
D.C✓ Correct
Explanation

Let us calculate the molarity and pH as follows- pH of 75 mL×M/5HCl+25 mL×M/5 NaOH. Total volume = 75 mL+25 mL=100 mL Number of mmol of HCl =75 mL×M/5=15 mmol Number of mmol of NaOH = 25 mL×M/5=5 mmol 5 mmol of NaOH will neutralise 5 mmol of HCl. Therefore, left mmoles of HCl will be- (15-5) mmol= 10 mmol. Now concentration of acidic protons= concentration of HCl 10 10 H HCl 10 mmol /100 mL 0.1 M pH log H pH log (0.1) M pH 1

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