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MEDIUMMCQ SINGLEJEE Advanced ChemistryPhysical ChemistryIonic equilibriumSalt Hydrolysis

A precipitate of AgCl is formed when equal volumes of the following are mixed. [Ksp for AgCl = 10 –10]

A.10
B.10
C.10✓ Correct
D.10
Explanation

3 3 AgNO HCl AgCl + HNO -> When equal volumes of 3 AgNO  and HCl are mixed, Resulting  Ag  and  Cl  in solution will be halved w.r.t. original concentration. Thus, in (a) 4 7 1 1 Ag 10 M Cl 10 M 2 2 x x Thus, 11 2 10 2 IP sp 1 K  = 10 M K 10 M 4 x (b) 5 6 1 1 Ag 10 M Cl 10 M 2 2 x x Thus, 11 2 10 2 IP sp 1 K  = 10 M K 10 M 4 x (c) 5 4 1 1 Ag 10 M Cl 10 M 2 2 x x Thus, 9 2 10 2 IP sp 1 K  = 10 M >K 10 M 4 x (d) 6 6 1 1 Ag 10 M Cl 10 M 2 2 x x

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