MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbonsPhysical & Chemical Properties of Alkynes

Identify a reagent from the following list which can easily distinguish between 1-butyne and 2-butyne.

A.bromine, CCl4
B.H2, Lindlar catalyst
C.dilute H2SO4, HgSO4
D.ammoniacal CuCl2solution✓ Correct
Explanation

1- butyne is a terminal alkyne.Terminal alkyne gives glacer coupling on reacting with ammonical copper CH3C CCH3 C C H CH3 H3C H (Cis) Lindlar’s Catalyst HYDROCARBONS 18 chloride solution. This formation of copper butylide gives red precipitates. 2 2 4 4 2 R-C C-H+Cu Cl +2NH OH R-C C-Cu +2NH Cl+2H O -> Aromatic Hydrocarbons

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