MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbonsPhysical & Chemical Properties of Alkenes
Which of the following will decolorise alkaline KMnO4 solution?
A.C3H8
B.CH4
C.CCl4
D.C2H4✓ Correct
Explanation
Alkenes on reaction with potassium permanganate gives vicinal glycols and brown colored precipitates of 2 MnO . The formation of these brown colored precipitates results in the discharge of pink colored 4 KMnO . C CH3 CH3 O + H3C C CH3 O O3 Zn/H2O C C R R R R KMnO4 (Colored) Pink C C R R R R OH OH MnO4 Decolored (Brown ppt.) Vicinal Glycols Alkenes + HYDROCARBONS 14
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