MEDIUMMCQ SINGLEJEE Mains ChemistryOrganic ChemistryHydrocarbonsPreparation & Properties of Alkanes
The highest boiling point is expected for
A.iso-butane
B.n-octane✓ Correct
C.2, 2, 3, 3-tetramethyl butane
D.2-methyl pentane
Explanation
n-octane has a more linear chain that corresponds to intermolecular forces of attraction. The structure of n- octane is as follows: 3 2 2 2 2 2 2 3 CH –CH –CH –CH –CH –CH –CH –CH Therefore,it has the highest boiling point.
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