Number of particles in system 1= system 2. i.e. ' ' 1 2 1 2 n n n n Also the given volume for two systems is equal. PV nRT / n PV RT Therefore, 1 1 1 2 1 2 1 1 2 / / / / 2 >> i i f f f i PV RT PV RT P V RT P V RT P V PV T T RT R T T 2 1 2 2 i f PT P T T
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