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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Physical ChemistryGaseous stateVan der Waals equation

The term that corrects for the attractive forces present in a real gas in the van der Waals’ equation is

A.nb
B.n2 a/V2✓ Correct
C.– (n2 a/ V2)
D.– nb
Explanation

The Vander Waal’s equation can be written as- 2 2 ( / )( ) P n a V V nb nRT The constant ‘a’ gives the measure of intermolecular forces of attraction. Hence, the pressure correction term which account for attractive forces in real gas is 2 2 n a V . The constant b gives the measure of molecular size.

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