MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryChemical kineticsElementary & Complex Reactions

For the reaction 2A + B ⟶ D + E the following mechanism has been proposed : A + B ⟶ C + D (slow) A + C ⟶ E (fast) The rate law expression for the reaction is

A.Rate = k [A]2 [B]
B.Rate = k [A] [B]✓ Correct
C.Rate = k [A] [C]
D.Rate = k [A]2 [B] [C]
Explanation

In a complex reaction, slowest step is rate determining step, thus A B C D -> is Rate determining step Thus, 1 1 Rate A B Rate = k A B

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