MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic ChemistryCarboxylic Acids and DerivativesCH CH CH Cl CO H

What will be the product, when carboxy phenol, obtained by Reimer-Tiemann’s process, is deoxidised with Zn-powder? (a) (b) (a) (b) (c) (d)

Answer
D
Explanation

The Reimer- Tiemann reaction is carried out on phenols in presence of chloroform and we obtain a hydroxybenzaldehyde as the end product. It proceeds through electrophilic substitution pathway. Salicylic acid obtained by Reimer- Tiemann reaction of phenol, upon deoxidation gives benzoic acid. The reaction is- Therefore, the correct answer is option – (d)

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