MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryAlkyl and Aryl HalidesE elimination follows an antiperiplanar structure

Θ Θ Θ Θ F,Cl,Br,I Among these nucleophiles, which of the following orders is correct for their nucleophilicity order in water? (a) Θ Θ Θ Θ F>Cl >Br>I (b) Θ Θ Θ Θ I>Br>Cl>F (c) Θ Θ Θ Θ I>Br>F>Cl (d) none of these

Answer
B
Explanation

Water is a protic polar solvent. The given options belong to the same group and nucleophilicity increases down the group in polar protic solvents. 13. For the following: (1) I– (2) Cl– (3) Br– the increasing order of nucleophilicity in polar protic solvent would be (a) I–< Br–< Cl– (b) Cl–< Br–< I– (c) I–< Cl–< Br– (d) Br–< Cl–< I– The given options belong to the same group and nucleophilicity increases down the group in polar protic solvents. Mechanisms of substitution reactions 14. The alkyl halide is converted into an alcohol by (a) Addition (b) Substitution (c) Dehydrohalogenation (d) Eli

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