MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryAldehydes and ketonesChemical Reactions of Carbonyl compounds
The most reactive compound towards formation of cyanohydrin on treatment with HCN followed by acidification is
A.benzaldehyde
B.p-nitrobenzaldehyde✓ Correct
C.phenylacetaldehyde
D.p-hydroxybenzaldehyde
Explanation
Cyanohydrin will be formed easily by those compounds in which electron withdrawing group is present. Electron withdrawing will have –I-Effect which will have more positive charge on the carbonyl carbon atom decreasing the electron density and increasing the tendency of the HCN to attack. So, from the given options in p-nitrobenzaldehyde, nitro group is electron withdrawing group.
Practice More Like This
Take chapter-wise tests, track your progress, and master Aldehydes and ketones.
Start Free Practice →