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MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistryThermodynamics and ThermochemistryIntroduction to Thermodynamics

The entropy change when two moles of ideal monoatomic gas is heated from 200°C to 300°C reversibly and isochorically?

A.3
B.5
D.3
Explanation

We know that, 2 2 v 1 1 T V S nC ln nR ln T V When volume is constant i.e. for isochoric process: 2 v 1 T S nC ln T Given, n = 2 moles. The gas is monoatomic gas, so, v 3 C R 2 2 1 T 300 C 300 273 K 573K T 200 C 200 273 K 473K So, 2 v 1 T S nC ln T 3 573 573 S 2 R ln 3R ln 2 473 473 >> x x

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