MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and ThermochemistryPrevious Year Questions

The heat of combustion of carbon to CO₂ is –393.5 kJ/mol. The heat released upon formation of 35.2 g of CO₂ from carbon and oxygen gas is (2015)

A.+ 315 kJ
B.– 630 kJ
C.– 3.15 kJ
D.– 315 kJ✓ Correct
Explanation

(None): Given: C(s) + O₂(g) → CO₂(g), ∆H = – 393.5 kJ/mol ⇒ Amount of heat released on formation of 44 g CO₂ = 393.5 kJ ∴ Amount of heat released on formation of 35.2 g of CO₂ = 393.5 44 × 35.2 = 314.8 ≈ 315 kJ Note: –ve or +ve sign considering the reaction is exothermic or endothermic.

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