MEDIUMMCQ SINGLEJEE Mains ChemistryPhysical ChemistryThermodynamics and ThermochemistryPrevious Year Questions

In which of the following reactions, standard reaction entropy change (∆S°) is positive and standard Gibbs energy change (∆G°) decreases sharply with increasing temperature? (2012)

A.C(graphite) + 1✓ Correct
B.CO(g) + 1
C.Mg(s) + 1
D.1
Explanation

C(graphite) + 1 2 O₂(g) → CO(g) ∆ng =1− 1 2 = 1 2 As amount of gaseous substance is increasing in the product side thus, ∆S is positive for this reaction. And we know that ∆G = ∆H – T∆S As ∆S is positive, thus increase in temperature will make the term (–T∆S) more negative and ∆G will decrease.

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