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MEDIUMMCQ SINGLENEET ChemistryPhysical ChemistrySolutionsOsmotic pressure in colligative properties

The Van’t Hoff factors i for an electrolyte which undergoes dissociation and association in solvents are respectively

A.greater than 1 and greater than 1
B.less than 1 and greater than 1
C.less than 1 and less than 1
D.greater than 1 and less than 1✓ Correct
Explanation

Van’t Hoff Factor is given by the following formula- No. of particles after dissociation/association No. of particles before dissociation/association i It is known that the number of particles increase on dissociation, hence, i > 1 and the number of particles decrease on association, hence, i < 1. Thus, the correct option is (d)

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