MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistrySolid statePrevious Year Questions

A solid is formed by two elements P and Q. The element Q forms cubic close packing and atoms of P occupy one third of tetrahedral voids. The formula of the compound is [AMU 2010]

A.PQ3 (b) P₃Q
C.P₂Q3✓ Correct
D.P₃Q2
Explanation

Effective number of Q for FCC = 4 since tetrahedral voids are equal to the double of atoms in FCC lattice, so no. of tetrahedral voids =8 Effective contribution of P, 1 8 8 3 3 p Z x Formulae of compound = 8 4 2 3 3 P Q PQ Hence the correct answer is option (c)

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