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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistrySolid stateOctahedral void at edge centre

In A+ B– ionic compound, radii of A+and B– ions are 180 pm and 187 pm respectively. The crystal structure of this compound will be

A.NaCl type
B.CsCl type✓ Correct
C.ZnS type
D.Similar to diamond
Explanation

Limiting radian Ratios r x r CN Shape ex 0.155 x 2 Linear BeF₂ 0.155 0.255 x 3 Planar AlC₃ triangular 0.225 0.414 x 4 Tetrahedron ZnS 0.414 0.732 x 6 Octahedron NaCl 0.732 0.996 x 8 Body centre cubic CsCl Here in given statement. / 0.96256 r r = CsCl type

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