MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic Chemistryp-Block (group 13 and 14)Previous Year Questions

The main reason that SiCl₄ is easily hydrolyzed as compared to CCl₄ is that (Kerala CEE 2009)

A.Si—Si bond is weaker.
B.SiCl₄ can form hydrogen bonds.
C.SiCl₄ is covalent.
D.Si can extend its coordination number beyond four.✓ Correct
Explanation

It is easily hydrolysed as compared to because in case of vacant d-orbitals are present, so Si can expand its valency but carbon does not have a vacant d-orbitals. Carbon can’t expand its valency. Hence, the correct option is (d).

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