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MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp -Block Elements (group 15-18)Previous Year Questions

Affinity for hydrogen decreases in the group from fluorine to iodine. Which of the halogen acids should have highest bond dissociation enthalpy? (AIIMS 2019)

A.HF✓ Correct
B.HCl
C.HBr
D.HI
Explanation

As the size of the halogen atom increases from F to I, H–X bond length in halogen acids also increases from H–F to HI. (HF<HCl < HBr < HI). The increases in HX P-BLOCK ELEMENTS (GROUP 15-18) 30 bond length decreases the strength of HX bond from HF to HI (HF > HCl > HBr > HI). Due to successive decreases in the strength of HX bonds, bond dissociation enthalpy decreases form HF to HI. HX: HF > HCl > HBr > HI Bond dissociation 574.0 428.1 362.5 294.6 enthalpy (kJ/ mol)

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