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MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp -Block Elements (group 15-18)Previous Year Questions

Which is the correct order of thermal stability for H₂E (E = O, S, Se, Te and Po)? (NEET 2019) (a) H O H S H Se H Te H Po (b) H Po H Te H Se H S H O (c) H Se H Te H Po H O H S (d) H S H O H Se H Te H Po

Answer
B
Explanation

For group 16 elements, the hydrides with higher molar mass (e.g. H₂PO) are less thermally stable than hydride with lower molar mass (e.g. H₂O). This is due to the increase in size of central atom which results to the weakening of M–H bond due to increased bond length. Thus, the correct order of thermal stability of H₃E(E = O, S, Se, Te and Po) is as follows: 2 2 2 2 2 H Po H Te H Se H S H O

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