MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp -Block Elements (group 15-18)Previous Year Questions

The correct order of N-compounds in its decreasing order of oxidation states is (NEET 2018)

A.HNO₃, NH₄Cl, NO, N₂ (b) HNO₃, NO, NH₄Cl, N₂
C.HNO₃, NO, N₂, NH₄Cl (d) NH₄Cl, N₂, NO, HNO₃✓ Correct
Explanation

Let the oxidation state of nitrogen in each of the given N-compound be x. (i) HNO₃ : + 1 + x + 3(–2) = 0 x = + 5 Oxidation state of N in HNO₃ is + 5. (ii) NO : + x + 1(–2) = 0 x = + 2 Oxidation state of N in NO is + 2. (iii) NH₄Cl : x + 4(+1) + 1(–1) = 0 x = – 3 Oxidation state of N in NH₄Cl is – 3. (iv) N₂ : x = 0 [ N₂ is present in elemental state] Oxidation state of N in N₂ is 0. Thus, the correct decreasing order of oxidation states of given N-compounds will be : 5 2 0 3 3 2 4 HNO NO N NH Cl

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