MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp -Block Elements (group 15-18)Previous Year Questions

Among the following compounds, which will produce POCl₃ with PCl₅? (JIPMER 2017)

A.Only O₂
B.O₂ and CO₂
C.CO₂, O₂ and P₄O₁₀
D.SO₂, H₂O, H₂SO₄,P₄O₁₀✓ Correct
Explanation

PCl₅ on reaction with the given compound produces POCl₃. 5 2 3 2 5 2 3 5 2 4 2 2 3 5 4 10 3 2PCl SO POCl SOCl PCl H O POCl 2HCl 2PCl H SO SO Cl 2POCl 2HCl 6PCl P O 10POCl → → → →

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