MEDIUMMCQ SINGLEJEE Advanced ChemistryInorganic Chemistryp -Block Elements (group 15-18)Previous Year Questions

The correct order of relative acidity is (UP CPMT 2013)

A.HClO > HClO₂ > HClO₃ > HClO₄
B.HClO₄ > HClO₃ > HClO₂ > HClO✓ Correct
C.HClO > HClO₄ > HClO₂ > HClO₃
D.HClO₃ > HClO₂ > HClO₄ > HClO
Explanation

Acidic strength of oxyacids increases with increases with increase in oxidation state in central atom. Find the oxidation state of chlorine in all the oxyacids to decide the decreasing acidic strength order among oxyacids. (i) HClO₄ = + 1 + x + (– 2 x 4) = 0 x = +7 (ii) HClO₃ = +1 + x + (– 2 x 3) = 0 x = + 5 (iii) HClO₂ = 1 + x + (–2 x 2) = 0 x = + 3 (iv) HClO = +1 + x + (– 2 x 1) = 0 x = + 1 HClO₄ is the strongest acid and HClO is the weakest acid. Correct order of acidic strength is HClO₄> HClO₃ > HClO₂ > HClO

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