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MEDIUMMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryMetallurgyExtraction of Gold and Silver

In the process of extraction of gold, Roasted gold ore + CN – + H₂O → [X] + HO – [X] + Zn → [Y] + Au Identify the complexes [X] and [Y]

A.X = [Au(CN)₂]✓ Correct
B.X = [Au(CN)₄]
C.X = [Au(CN)₂]
D.X = [Au(CN)₄]
Explanation

The process of extraction of gold involves the following reaction: - - 2 2 Roasted gold ore+CN +H O [Au(CN) ] +HO → - - 2 4 [Au(CN) ] +Zn Zn[(CN) ] +Au → So from the equations: X = - 2 [Au(CN) ] and Y = 2- 4 [Zn(CN) ] METALLURGY 37

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