HARDMCQ SINGLEIChO (Chemistry Olympiad)Organic ChemistryHydrocarbonsAchiever Section
When hydrochloric acid gas is treated with propene in presence of benzoyl peroxide, it gives.
A.2-Chloropropane✓ Correct
B.Allyl chloride
C.O C. No reaction
D.n-Propyl chloride
Explanation
Peroxide effect is observed only in case of HBr. Therefore, addition of CHl to propene even in the presence of benzoyl peroxide occurs according to Markovnikov's rule: HCl CH CH CH CH CHCl CH 3 2 3 3 (C H CO) O 5 6 2 2 →
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